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Characteristics and Source Apportionment of Atmospheric Volatile Organic Compounds of Tai’an Urban Area in Autumn
WANG Lu, ZHOU Xu, LIU Yuehui, LIU Hui, ZHANG Yinglei, FAN Guangyu
Acta Scientiarum Naturalium Universitatis Pekinensis    2024, 60 (2): 329-340.   DOI: 10.13209/j.0479-8023.2024.007
Abstract73)   HTML    PDF(pc) (1184KB)(26)       Save
The preconcentration/gas chromatography-mass spectrometry with FID detector method was used to observe the 115 atmospheric volatile organic compounds (VOCs) of Tai’an urban area in autumn 2020. The average volume fraction of VOCs during the observation period was (67.50±25.55)×10−9, dominated by alkanes (34.86%) and oxygenated volatile organic compounds (OVOCs) (32.03%). The atmospheric chemistry reactivity of VOCs was estimated using ozone formation potential (OFP) and the OH radical loss rate (LOH), respectively. The OFP of Tai’an in autumn was (241.50±6.91)×10−9, mainly contributed by OVOCs (39.92%) and aromatics (33.03%). The calculated LOH was 7.34±0.33 s−1, which was dominated by OVOCs (56.32%). The contribution of VOCs to the potential for secondary organic aerosol (SOA) formation was estimated using the fractional aerosol coefficients (FAC), and the results showed that SOA formation potential was (366.58±37.80)×10−9, dominated by aromatics (98.79%). The results of the characteristic species ratio analysis showed that the VOCs of Tai’an in autumn were influenced by local sources such as traffic-related emissions, solvent use and combustion sources. The source apportionment results showed that the contribution of motor vehicle emissions to VOCs was the highest at 26.1%, with the contributions from gasoline vehicle exhaust emissions and diesel vehicle exhaust emissions being 19.4% and 6.7%. The contribution of solvent use and industrial sources to VOCs was comparable at 20.1% and 19.9%, respectively. The contribution of stationary combustion sources and liquefied petroleum gas (LPG) use was 16.2% and 12.3%, respectively. Biogenic sources contributed the lowest percentage of 5.4%.
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Study of the Spherical Fossils from the Ediacaran-Cambrian Liuchapo Formation in Guizhou, China
LIU Hui, DONG Lin
Acta Scientiarum Naturalium Universitatis Pekinensis    2023, 59 (3): 427-433.   DOI: 10.13209/j.0479-8023.2023.016
Abstract204)   HTML    PDF(pc) (680KB)(88)       Save
Microfossils from cherts of the Liuchapo Formation at Bahuang section in eastern Guizhou Province were studied. Through thin section observation, a large number of spherical fossils were revealed, including one type with connected spheroids, and two types with dark outer wall. The former is systematically described, and a new genus Bahuangia gen. nov. is established. The connected bodies of Bahuangia are calabash- or chain-shaped, and resemble the budding unicellular fungi or bacteria in morphology. Spherical fossils similar to these Bahuang specimens are widely distributed in the late Ediacaran deep-water facies of the Yangtze Plate. Through this study, the understanding of deep-water life forms during the ECT is improved, and new materials for both regional stratigraphic correlation and early life evolution are provided.
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Three Dimensional Dynamic Simulation Method of Toxic Gas Leakage Accident Based on CALPUFF Model: A Case Study of Kaixian Blowout Accident 
ZHANG Rongqian, LI Mei, YANG Dong’ou, LIU Hui
Acta Scientiarum Naturalium Universitatis Pekinensis    2022, 58 (6): 1042-1054.   DOI: 10.13209/j.0479-8023.2022.094
Abstract624)   HTML    PDF(pc) (54291KB)(144)       Save
Aiming at the problems in the current emergency management GIS systems integrated with atmospheric dispersion models, such as low spatio-temporal resolution and without 3D terrain, a set of three-dimensional gas diffusion simulation methods was proposed based on the CALPUFF model. The three-dimensional spatio-temporal distribution data of the gas diffusion concentration was obtained through multi-layer calculations, and the Marching Cubes visualization technology was used to read and display the data, achieving the dynamic gas diffusion effect in three-dimensional space. “12·23” Kaixian blowout accident was used as a case study and the simulation was carried out to compare with the actual situation in two and three dimensions. The results show that the three-dimensional calculation based on CALPUFF model has higher accuracy of the magnitude and spatial distribution of gas concentration, and the three dimensional spatio-temporal dynamic simulation has high resolution and reconstruction efficiency, achieving a good visual effect. It can better express the gas leakage process and diffusion pattern and provide an important auxiliary decision-making means for emergency management.
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Paleoenvironment Interpretation of Early Cambrian Yurtus Formation, Tarim Basin, and Its Mechanism for Organic Carbon Accumulation
WANG Zhihong, DING Weiming, LI Jian, HAO Cuiguo, LIU Hui, LI Tong, DONG Lin
Acta Scientiarum Naturalium Universitatis Pekinensis    2020, 56 (4): 667-678.   DOI: 10.13209/j.0479-8023.2020.045
Abstract1267)   HTML    PDF(pc) (26226KB)(113)       Save
This study scrutinizes the petrological and geochemical signatures by systematically sampling three sections of Yurtus Formation, which deposited during the early Cambrian in the western margin of Tarim Basin. The redox conditions together with the intensity of primary productivity during Yurtus Formation deposition are reconstructed, which provide theoretical basis for the distribution of source rocks and evaluation of reservoir potentials. The extremely high Ba content (>1000 μg/g) and appearance of barite in the lower part of Yurtus Formation implies high primary productivity, which explains the substantive organic matter in the surface ocean and is also consistent with the abundant phytoplankton fossil record and high TOC content. The large positive excursion of δ15N (>8‰) in the lower parts of Yurtus Formation probably is resulted from denitrification or annamox, both of which occur only when O2 is depleted. It may indicate that organic matter transporting from the surface ocean to deeper ocean could consume dissolved oxygen by the process of degradation, which would drive the condition of deeper ocean more reduced. Meanwhile, low Ge/Si values of cherts in the lower part of Yurtus Formation indicate normal seawater origin of Si input. Oversaturation state of silica promotes the organic matter preservation due to relatively fast cementation. 
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Systematic Optimization and Scenario Analysis of Social Economy and Environment in Dianchi Watershed
SHENG Hu,LIU Hui,WANG Cuiyu,GUO Huaicheng
Acta Scientiarum Naturalium Universitatis Pekinensis   
Estimation of the Soil Moisture Using FY-3A/MWRI Data over Semiarid Areas
PENG Lichun,LI Wanbiao,LIU Huizhi
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract645)      PDF(pc) (535KB)(282)       Save
In order to monitor the range and extent of drought and resolve the serious problems of the semi-arid regions, a soil moisture retrieval method by satellite microwave remote sensing is proposed. The relation of microwave brightness temperature and surface soil moisture was simulated by surface and atmosphere microwave radiative transfer models. The soil moisture retrieval algorithm in the logarithm-cubic form was established. By using the data of the microwave radiation imager aboard the FY-3A polar orbiting meteorological satellite and the retrieval algorithm, the soil moisture was derived for the farmland and the grassland in Tongyu of Jilin. The result shows that the retrieval soil moisture is in good agreement with the ground-based observations. The root mean square error is 0.003 cm3/cm3 for the farmland, and 0.005 cm3/cm3 for grassland. The method can be applied to the future FY-3B satellite that is possible to derive more information. With the improved radiation transfer model in the future, the radiation characteristics of the various grounds will be obtained. The regional moisture study will be carried on in the future.
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Environmental Changes at the North of Jianghan Plain during Ming and Qing Period
ZHONG Yujia,MO Duowen,LI Yiyin,SHI Chenxi,HU Ke,LIU Hui
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract672)            Save
The Caidangxi profile is in the north of Jianghan Plain, Hubei Province, China. Synthetic analysis of grain size, chemical elements and pollen of sedimentary samples from Caidangxi profile reveal the paleo-environmental changes since 1250 AD of the area. The sediments of the profile dominantly consist of clay silts. The sedimentary characteristics, such as grain size and the sorting coefficient, together with the analysis geomorphic position on which the deposition occurred, may indicate that the sediments were deposited by sheet flood mainly from Han River in a slow hydrodynamic depositional process. The sedimentary characteristics also show some similarities with the loess sediments for that some materials were derived from the loess distributed in this river basin. The grain-size and sorting have a significantly increase in 1500 AD, which might reflect the effect of the intensified flooding process. The climatic history since 1250 AD could be identified four stages by geochemical elements and pollen analysis data. The climate of four stages were respectively “wet and warm”, “cool and dry”, “a little wet and warm” and “a little cool and dry”. The distinct cool and dry climate during around 1500 AD might reflect the response of an evidently lower temperature event of the Little Ice Age. It also might be one of the reasons for the intensified flood process during the same time.
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Analysis of the Surface Temperature over Keerqin Sand Aera in Inner Mongolia
ZHANG Peng,ZHANG Hongsheng,DU Jinlin,LIU Huizhi
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract886)            Save
Using the micrometeorological data obtained over the moving sand dune in Keerqin sand area in Inner Mongolia in summer of 2001 and spring of 2002, the surface temperature was determined and the characteristics were analyzed over the sand dune area. The idea is using discrete Fourier transform on the temperatures of different layers and applying soil heat conduction equation. The results are that soil temperature conductivity ratios which are calculated from the decline of the soil temperature amplitude and phase difference agree well under the assumption of layered homogeneity. The surface temperature was calculated using the relationship of the soil temperature conductivity ratios at different depths and the amplitude and phase of dominant and harmonic frequencies of soil temperature. The surface temperatures calculated from observed soil temperatures at 5 cm and 10 cm depth show a good agreement. The amplitude of soil temperature waves decreases exponentially with depth. The diurnal variation of soil temperature at 80 cm is small.
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An Integrated Methodology Framework for Cumulative Environmental Assessment of Regional Development Plan
DU Xiaoshang,LIU Yong,GUO Huaicheng,LIU Hui,YANG Pingjian,YANG Yonghui
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract754)            Save
An integrated methodology framework was proposed to acknowledge the important role of cumulative environmental assessment (CEA) in the strategic environmental assessment of regional development plan (RDP). The developed CEA framework consisted of nine steps, including (a) analysis of regional development plan, (b) identification of environmental responses, (c) determination of CEA scales, (d) network analysis of pressures and responses, (e)baselines for CEA, (f) scenarios development, (g) cumulative assessment and early warning, (h) mitigative measures of environmental consequences, and (i) adaptive management. Scenario analysis and system dynamic (SD) models were integrated to deal with the uncertainties and dynamics in the RDP system. The cumulative environmental consequences at various temporal and spatial scales were assessed using the integrated models. The RDP of Zhengzhou Airport Zone (ZZAZ) was taken as a case and its CEA and early warning for regional air and ground water was carried out. Four scenarios were proposed after the comprehensive of ZZAZ’s RDP and the identification of environmental consequences. System dynamic model was developed for temporal and spatial CEA, combined with air and water mechanistic models. Several strategies were proposed based on CEA results to mitigate the consequences, including (a) adjustment of spatial ecological patterns at regional scale, (b) optimization of regional industries structure, (c) pollution control, and (d) adaptive management.
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Driving Forces Analysis of Housing Price in Beijing City
HE Chengjie,GUO Huaicheng,WANG Zhen,YANG Yonghui,LIU Hui,SHENG Hu
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract596)            Save
Multivariate statistical analysis and hedonic pricing method were employed to analyze the effects of structural variables, including land transaction price, bus lines, distance to downtown area, central business district, railway station and hospital, floor area ratio (FAR), and dichotomous variables, including nearness to rail transit, recreational facilities and parks on housing transaction price in Beijing city. Results indicate that the main determinants of real estate price in Beijing are land transaction price, distance to downtown area, FAR, existence of nearby rail transit and recreational facilities. Among which, land transaction price have a considerably positive effect on transaction price, while FAR and distance from housing to the downtown area are the main negative driving forces for housing transaction price in Beijing.
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Estimation of the Net Radiation over Arid and Semiarid Areas Only Using MODIS Data for Clear Sky Days
YE Jing,LIU Huizhi,LI Wanbiao,CAI Shuangpeng,LI Yuming,CAO Lixia
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract818)            Save
Based on the parameterization of downward shortwave radiation, upward shortwave radiation, downward longwave radiation and upward longwave radiation above the surface, a scheme is proposed to estimate instantaneous net radiation over arid and semiarid areas for clear sky days using only remote sensing observations. The scheme attempts to eliminate the need for ground meteorology data as the estimates of land surface radiation balance, by using various land and atmospheric data products available from moderate resolution imaging spectroradiometer(MODIS). The preliminary results, using 89 cases over the degraded grassland and 85 cases over the farmland during July to October in 2003, July to November in 2004 and June to October in 2005, show good agreement with ground-based observations, with the root mean square error of 47. 5 and 49. 2 W/m2 respectively, which have better accuracies than the other similar studies.
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Study on Optimization of Urban Passenger Traffic Environmental SystemBased on Trip
LIU Hui,GUO Huaicheng,YU Yajuan,WANG Zhen,LIU Tao
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract664)            Save
An optimization model was developed for urban traffic environmental system based on passenger trip generating.Firstly, a System Dynamic model was built up to simulate the developing characteristics of urban passenger traffic system, as well as its environmental impacts. Secondly, a linear optimization model, with the objective of maximizing traffic efficiency under the resource and the environment constrains, was formed to search for the best trip assignment structure. Thirdly, several scenarios were designed based on the results of the two former models and amending effects were re-simulated. Finally, grey correlation assessment was utilized on the premise of social-economic support, feasible policy, minimized pressures on resource and environment, to select the optimized assignment structure. Acase study of Beijing wasfollowed andtheresults verified the mode's effectiveness.
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Determination of Atmospheric Boundary Layer Height in Unstable Conditions over the Middle Tibetan Plateau
SONG Xingzhuo,ZHANG Hongsheng,LIU Xinjian,FAN Shaohua,LIU Huizhi,HU Fei,LI Shiming,ZHOU Mingyu,BIAN Lingen,XU Xiangde
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract744)            Save
The atmospheric boundary layer (ABL) height zi in unstable condition was analyzed using turbulence data from Damxung observational station, which was one of the ABL observational stations in the second Tibet Plateau Experiment (TIPEX) in 1998. Together with the observational vertical profiles of temperatures, the authors studied the diurnal and seasonal evolution characteristics of the ABL over the Tibet Plateau, analyzed both differences and similarities of the ABL between dry and wet seasons, and explored the terrain influence on the ABL height. The results show that the ABL over Tibet Plateau has the characteristics of development and lasting over a longer time.
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A Study of the Microwave Radiance and Lightning Characters of Mesoscale Convective Systems
CAO Zhiqiang,LIU Huizhi,LI Wanbiao,TONG Ke,NIU Xiaolei
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract633)            Save
Through the analysis of 11 typical mesoscale convective systems occurring at China continent and adjacent ocean on June, July and August, 1998, it is found that 10.65GHz_ V channel and 19.35GHz_ V channel can well response to the absorbability and emission of liquid water in cloud and precipitation, and that 85.5GHz_ V channel and 37.00GHz_ V channel can response to the ice scatting in cloud well. Based on these characters of MCS, the relationship between 85.50GHz polarization-corrected temperatures (TPC) and lightening is further discussed. The results show that large events density occurred within the contour of 220K, and that during 220--260K, the events density is sharply reduced. At TPC higher than 260K, there is almost no events observed.
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Estimating Land Surface Temperature of Huaihe River Basin from TRMM and GMS-5 Satellite
NIU Xiaolei,ZHOU Wei,LIU Huizhi,LI Wanbiao
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract667)            Save
The equation for estimating land surface temperature of Huaihe River Basin has been set up by using the data of split window channels of TRMM and GMS-5 satellite and the ground observation data of HUBEX. Comparison with the ground observation data of Huaihe River Basin from many aspects shows the result is in good agreement with observation. On the basis of the typical weather situation in Huaihe River Basin in 1998, the paper analyses the features of the land temperature of Huaihe River Basin in the four stages of the 1998's Meiyu of Yangtze.
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Influences of Structures on Urban Ventilation: A Numerical Experiment
JIANG Yujun,SANG Jianguo,LIU Huizhi,ZHANG Boyin
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract590)            Save
The disturbed flow caused by three six-storied residential buildings and a twenty-storied tall tower, respectively, as well as the distribution of traffic tail gas from a nearby road, are simulated by using an urban climate model. The results show that with the same built areas the ventilation ability of the atmospheric environment around the tall tower is better than that around the multi-storied buildings.
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The Characteristics of Dissipation Rates of Turbulent Variance over Damxung Area in the TIbetan Plateau
LI Fuyu,ZHANG Hongsheng,LI Shiming,ZHOU Mingyu,CHEN Jiayi,XU Xiangde,LIU Huizhi,HU Fei
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract793)            Save
The turbulent data obtained from Damxung site during TIPEX in 1998 were used to study the characteristics of dissipation rates of turbulent kinetic energy, temperature variance and humidity variance in the middle area of Tibetan Plateau. The results indicate that the dimensionless dissipation rates of turbulent energy are 20% less than the energy produced by velocity shear, and the dimensionless temperature and humidity variances are also 20% less than the variances produced by temperature and humidity gradients. These deficits appear to increase with the increasing of the absolute stability parameter. Moreover, the effects of turbulent transportation and pressure variance, which are related with the stability parameter, persist throughout the whole stability region. The differences between these results and some previous studies show the underlying-surface-dependant characteristics of the dissipation rates of turbulent energy, temperature variance and humidity variance.
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Numerical Simulation of Dynamic and Thermal Field over 2-D Urban Street Canyon
WANG Baomin,SUN Xiangming,LIU Huizhi,SANG Jianguo
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract629)            Save
The dynamic sub model ARPS is improved to simulate the flow field over two-dimensional street canyons. An energy budget sub model coupled with the modified ARPS is developed to compute the thermal structure. The dynamic sub model is capable of describing those characteristic flows around the buildings, including vortices between buildings and lee vortices, etc., while the coupling model can be used to simulate the diurnal variations of energy budget of different facades and temperature. These cases studies indicate that the above model systems can be used for investigating the wind and thermal environment and the processes of air pollutant transportation and diffusion over a street canyon or a group of buildings.
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Turbulence Length Scales, Dissipation Rates and Structure Parameters above the Forest Canopy
LIU Shuhua,HU Fei,LIU Huizhi,XU M,ZHU Tingyao,JIN Changjie
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract740)            Save
The turbulent data were measured using three-dimensional sonic anemometers/thermometers above a forest canopy, in the Changbai Mountains of northeast China. Turbulence length scales, dissipation rates and structure parameters above the forest canopy were calculated using the eddy correlation method. Results show that the turbulence characteristic length scales for momentum are negative interrelated with Z/L number; the turbulence characteristic length scales for heat is positive interrelated with Z/L number in unstable air and that is negative interrelated with Z/L number in stable air. The agreement between the momentum and heat dissipation rates calculated directly from the w spectrum(the turbulence spectral method)and indirectly from equations(15)(16)are quite good. The dimensionless turbulence structure functions C2vz2/3σw-2 and C2Tz2/3σT-2 are functions of Richardson number in stable and unstable air. Turbulence structure parameters C2T has a direct linear bearing on the sensible heat flux w'T'.
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Meso-scale Atmospheric Diffusion Patterns and Time Scales over Beijing Area
GUO Yu,CAI Xuhui,LIU Huizhi,CHEN Jiayi
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract712)            Save
Spatial distribution and time scales of atmospheric diffusion over Beijing area are revealed by means of a random walk simulation model and practical meteorological data with a specified emission source from the city. Results show a southward transport pattern for wintertime while a northwest transport of pollutants in summer. The area is the least evidently influenced by the emission source in spring, while the largest in autumn.The time spent for instantly emitted material removing from the model domain varies from winter-spring to summer-autumn. The former was shorter one of less than 20 hours; the latter was longer one of approximately 30 hours. Distribution of occurrence probability for different removal times was not symmetry.Reducing slowly at the end of longer removal time, probability exists for pollutants remaining in this area a long time.
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Flow Patterns of Lower Atmosphere over Beijing Area
CAI Xuhui,GUO Yu,LIU Huizhi,CHEN Jiayi
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract665)            Save
Wind-field diagnostic analysis and historical observation data are used to reveal general flow patterns of lower atmosphere over Beijing area. The preliminary results show that air flows in this area could be classified into autumn-winter pattern and spring-summer pattern. The former is under effect of more strong synoptic systems, while the latter shows more characteristics of mesoscale thermal circulation induced by topography. The mesoscale circulation determines basic air flow patterns in this area, which is typical in spring-summer season and in calm weather of autumn-winter season. Air flow under strong wind condition in autumn-winter season is seriously perturbed by topography. The perturbation displays as a horizontal vortex covering whole city of Beijing and part of mountain area in northwest.
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Combined Wavelet Transform with Neural Network for Oscillographic Chronopotentiometric Determination
ZHENG Jianbin,ZHANG Jun,LIU Hui,ZHONG Hongbo,LI Guanbin,CHEN Liren
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract624)            Save
Combination of wavelet transform with function of data compression and neural network is firstly applied to predict quantitatively the concentration of Pb2+ and other ions in oscillographic chronopotentiometric determination(OCPD). Compared with RPNN and WNN, combination of the wavelet transform and neural network(CWTNN)for OCPD has higher prediction accuracy and less convergence epoch. This can be explained from two aspects. Firstly, the network operation rate has been greatly enhanced because the optimal detail signal obtained after the wavelet transform not only is the characteristic information in original signal, but also has less number of data points than that of original signal. Secondly, the higher prediction accuracy can be obtained because detail signal used as network input contains lower noise. As a result, the potential application of CWTNN for OCPD and other electroanalytical methods will be very excellent.
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Study on Fluorescence Spectroscopy of Terbium(Ⅲ) Complexes with DTPAA Anhydride and pAS-Na in Aqueous Solution
ZHANG Yuanjing,LIU Qinde,WANG Xiaogang,CHEN Yu,LIU Hui,LI Junran
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract718)            Save
The Tb3+ mixed ligand complex was prepared using Tb3+, DTPAA and pAS-Na in aqueous solution, and its existence was proved by UV and fluorescence spectra. The influence of concentration, pH value and La3+ on fluorescence emission strength of the complex was studied. The reaction of DTPAA with pAS-Na can give DTPA-pAS and DTPA-2pAS. Their Tb3+ complexes were obtained via the reactions of Tb3+ with DTPA-pAS and DTPA-2pAS in aqueous solution, respectively. The fluorescence properties of the Tb3+ complexes were studied. The possibility for application of the Tb3+ mixed ligand complex in labeling for human serum albumin(HSA) is tested.
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The Two Dimensional Numerical Simulation of Temperatureand Humidity Profiles Structure of Atmospheric Boundary Layer over Gobi Underlying Surface
LIU Shuhua,HONG Zhongxiang,LI Jun,LIU Huizhi
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract1042)            Save
In this paper, the two-dimensional numerical model are used for simulating the profiles of the potential temperature and specific humidity over homogeneous Gobi underlying surface under convective conditions. This result explains the observed fact that most of the profiles of the potential temperature and specific humidity. The model also gives a fair description of the time variation of the profiles of the potential temperature and specific humidity and the depth of the mixed layer. Comparison with observation shows that the results obtained from the numerical model are in good agreement with observations of the potential temperature and specific humidity, including the change of the depth of the mixed layer with time.
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